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Biosketch
Experience
2021 - Present Inspire Faculty Fellow, Indian Institute of Technology, Palakkad, Kerala, India
2019 - 2020 - Inspire Faculty Fellow, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore, India
2016 - 2018 - PostDoctoral Researcher in Prof. Roald Hoffmann Group, Cornell University, Ithaca, USAEducation
2016 - Phd (IISER Trivandrum) Research supervisor: Prof. E. D. Jemmis -
Research
Theoretical and Computational Chemistry, Material Chemistry
The broader theme of our research is chemical bonding across the periodic table. We try to understand the factors deciding the structure, bonding, reactivity, and properties of compounds because that knowledge will allow us to tune these factors in a desirable way. We translate the concepts of molecular chemistry to extended solid-state structures, with the intention to make Material Chemistry friendlier to chemists. This way, we are trying to tackle relevant technological problems such as the instability issues of lead iodide-based perovskites, which hinder the commercialization of perovskite-based solar cells. We also try to design new materials which can be potential solar absorbers and can be a good substitute for unstable and toxic lead iodide-based perovskites. We also work on materials that exhibit the property of photo-induced phase transition and self-healing
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Teaching
CY1020: Theoretical and Inorganic Chemistry, 2021, 2022
CY1011: Thermodynamics, kinetics and Organic Reactions 2020, 2021
BTech Lab 2021
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Research Group
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Ashith T - Research Assistant, Sept. 2021 -
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Athul B K - M. Sc. Project, 2023
Alumni -
Mithu Kumari - M. Sc. Project 2021 ( pursuing Phd at IIT Dhanbad (ISM) )
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Rajani - M. Sc. Project 2021
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Samridhi S - M. Sc. Project 2022
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Krishnapriya K C, Post Doc, Feb. 2022 - Feb. 2023, ( Postdoc now in Sweden )
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Additional Information
TitlePublicationsDescription
At IIT Palakkad
Subila K. B., Priyakumari C. P., Lothar H., Maor A., Omer Y., and Eran E
Revealing hidden phases and self-healing in antimony trichalcogenides and chalcoiodides
Cell Rep. Phys. Sci. 2023 4, 101298https://doi.org/10.1016/j.xcrp.2023.101298
Ashith T., and Priyakumari C. P.*
Lewis Acidity Trend of Boron and Aluminium Trihalides: If Not π Back-Bonding, What Else?
ChemPhysChem 2023. (24), 5, e202200761, https://doi.org/10.1002/cphc.202200761Priyakumari C. P.* and Sathya S. R. R. Perumal.
On the Instability of Iodides of Heavy Main Group Atoms in their Higher Oxidation State
Phys. Chem. Chem. Phys. 2023, 2023,25, 6306-6315
https://doi.org/10.1039/D3CP00014AM. Usha, K. Sreeja, U. Rajeena, C. P. Priyakumari, P. Raveendran, M. R. Resmi,
Preparation of mesoporous poly(fullerene oxide) framework by thermal [3 + 2] cycloadditions and its application as a semiconductor photocatalyst.
Fullerenes, Nanotubes and Carbon Nanostructures, 2022 , 10.1080/1536383X.2022.2152440Subila K. B., Priyakumari C. P., and Eran E.
Mechanistic Insight into the Topotactic Transformation of Trichalcogenides to Chalcohalides.
Chem. Mater. 2022, 34, 7, 3468-3478 https://doi.org/10.1021/acs.chemmater.2c00306
This work was chosen for cover page graphics-
While at IISc, Bengaluru
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Priyakumari C. P. and Sathya S. R. R. Perumal,
Lewis Base/Acid Coordination Stabilizes Planar 6π Aromatic Si6/P6
Organometallics, 2020, 39, 16, 2951-2955
https://doi.org/10.1021/acs.organomet.0c00449While at Cornell University
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Priyakumari C. P. and R. Hoffmann,
Alkyl Isosteres,
J. Am. Chem. Soc. 2018, 140 (40), 12844–12852,
https://doi.org/10.1021/jacs.8b06141 -
Priyakumari C. P. and R. Hoffmann,
Donor-Acceptor Strategies to Stabilize a Planar- Diplumbene,
Organometallics 2017, 36 (24), 4825–4833.6
https://doi.org/10.1021/acs.organomet.7b00733 -
A. M. Rawashdeh, Priyakumari C. P., T. Zeng, and R. Hoffmann,
An Iodabenzene Story,
J. Am. Chem. Soc. 2017, 139 (20), 7124–7129
https://doi.org/10.1021/jacs.7b03388
An interesting chronicle about this work can be found here
While at IISER Trivandrum -
C. P. Priyakumari, and E. D. Jemmis,
Computational design of oligo-sulfuranes,
J. Chem. Sci. 2016, 128, 1663–166
https://doi.org/10.1007/s12039-016-1157-2 -
C. P. Priyakumari and E. D. Jemmis,
Electron Counting Rules in Cluster Bonding -Polyhedral Boranes, Elemental Boron, and Boron-Rich Solids, in The Chemical Bond: Chemical Bonding Across the Periodic Table, Ed., G. Frenking, S. Shaik, pp. 113-147, Wiley-VCH, 2014
https://doi.org/10.1002/9783527664658.ch5 -
C. P. Priyakumari, E. D. Jemmis,
P 3 F 92- An all-pseudo-π* 2π-aromatic
J. Am. Chem. Soc. 2013, 135, 16026-16029
https://doi.org/10.1021/ja408308g
This paper was highlighted in chemistryviews, a popular science portal
https://www.chemistryviews.org/details/news/5337741/New_Evidence_for_CO_and_PF3_Analogy.html
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Publications
Subila K. B., Priyakumari C. P., Lothar H., Maor A., Omer Y., and Eran ECell Rep. Phys. Sci. 4 101298 (2023)Priyakumari C. P.* and Sathya S. R. R. PerumalPhys. Chem. Chem. Phys. 25 6306-6315 (2023)Ashith T., and Priyakumari C. P.*ChemPhysChem 24 (5) e202200761 (2023)M. Usha, K. Sreeja, U. Rajeena, Priyakumari C. P., P. Raveendran, M. R. ResmiFullerenes, Nanotubes and Carbon Nanostructures. (Taylor & Francis) (2022)Subila K. B., Priyakumari C. P., and Edri E.Chem. Mater. 34 (7) 3468-3478 (2022)Priyakumari C. P.* and Sathya S. R. R. Perumal*Organometallics, , 39 39 (16) 2951-2955 (2020)A. M. Rawashdeh, Priyakumari C. P., T. Zeng, and R. HoffmannJ. Am. Chem. Soc. 139 (20) 7124–7129 (2017)Priyakumari C. P. and R. HoffmannOrganometallics 36 (24) 4825–4833 (2017)C. P. Priyakumari, and E. D. JemmisJ. Chem. Sci. 128 1663–1669 (2016)C. P. Priyakumari and E. D. JemmisWiley-VCH 113-147 (2014)C. P. Priyakumari, E. D. JemmisJ. Am. Chem. Soc. 135 16026-16029 (2013)
